Atomic and Molecular Manipulation 1st Edition by Andrew Mayne, Gérald Dujardin 0080963552 9780080963556

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ISBN 10: 0080963552

ISBN 13: 9780080963556

Author: Andrew J. Mayne, Gérald Dujardin

 

Work with individual atoms and molecules aims to demonstrate that miniaturized electronic, optical, magnetic, and mechanical devices can operate ultimately even at the level of a single atom or molecule. As such, atomic and molecular manipulation has played an emblematic role in the development of the field of nanoscience. New methods based on the use of the scanning tunnelling microscope (STM) have been developed to characterize and manipulate all the degrees of freedom of individual atoms and molecules with an unprecedented precision. In the meantime, new concepts have emerged to design molecules and substrates having specific optical, mechanical and electronic functions, thus opening the way to the fabrication of real nano-machines. Manipulation of individual atoms and molecules has also opened up completely new areas of research and knowledge, raising fundamental questions of “Optics at the atomic scale”, “Mechanics at the atomic scale”, Electronics at the atomic scale”, “Quantum physics at the atomic scale”, and “Chemistry at the atomic scale”. This book aims to illustrate the main aspects of this ongoing scientific adventure and to anticipate the major challenges for the future in “Atomic and molecular manipulation” from fundamental knowledge to the fabrication of atomic-scale devices.

• Provides a broad overview of the field to aid those new and entering into this research area
• Presents a review of the historical development and evolution of the field
• Offers a clear personalized view of current scanning probe microscopy research from world experts

Atomic and Molecular Manipulation 1st Table of contents:

Chapter 1: Introduction

References

Part I: Electronics at the Atomic-Scale

Chapter 2 : STM Manipulation of Single Atoms and Molecules on Insulating Films

Introduction

Ultrathin insulating films

Interface state in NaCl/Cu(111)

Manipulation of metal atoms

Controlling the Charge State

Vertical Transfer and Build-up of Nanostructures

Imaging molecular orbitals

Manipulation of molecules: Molecular/orbital engineering

Manipulation of a Small Molecule: Water Dissociation on MgO Films

Organometallic Synthesis: Au-Pentacene

Metal-Ligand Complex Formation

Molecular Switching Based on a Tautomerization Reaction

Conclusion

References

Chapter 3: Electron Transfer Phenomena at the Molecular Scale: Organic Charge Transfer Complexes on

Introduction

TCNQ on Au(111): The neutral adsorption of an electron acceptor molecule

TTF on Au(111): Formation of a Wigner molecular lattice

TTF Nucleation: Long-Range Repulsive Versus Short-Range Attractive Interactions

TTF-TCNQ on Au(111): Molecular magnetism induced by CT

Conclusions and remarks

References

Part II: Chemistry at the Atomic-Scale

Chapter 4: Imprinting Atomic and Molecular Patterns

Single-molecule imprinting on semiconductors

Localized Atomic Reaction

Single Dissociative Attachment 1: Diatomic Molecules at Si(100)-2×1

Single Dissociative Attachment 2: Dissociative Attachment of Polyatomics

Discussion of Single Dissociative Attachment

Multiple Dissociative Attachment

Single-molecule imprinting on metals

LAR on Metals

Self-assembly followed by pattern imprinting

Imprinting Circles

Forming Lines

Imprinting Lines

Modes of reaction

Direct and Indirect Reaction

Cooperative Reaction

Chain Reaction

Recoil Reaction

Conclusion

Acknowledgements

References

Chapter 5: Tunnel-Current Induced STM Atomic Manipulation

Introduction

Experimental methods

Frame-by-Frame Scanning

Single-Point Current Injection

Desorption

DIET and DIMET

Si(100)-2×1:H

Chlorobenzene/Si(111)-7×7

Intramolecular bond dissociation

O2/Pt(111)

Chlorobenzene/Si(111)7×7

Fluoropentane/Si(100)

Nonlocal manipulation

CH3SSCH3/Au(111)

Chlorobenzene/Si(111)-7×7

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