Bioinspired Catalysis Metal Sulfur Complexes 1st Edition by Wolfgang Weigand, Philippe Schollhammer 9783527333080 3527333088

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Product details:

ISBN 10: 3527333088

ISBN 13: 9783527333080

Author: Wolfgang Weigand, Philippe Schollhammer

This book provides an overview of bioinspired metal-sulfur catalysis by covering structures, activities and model complexes of enzymes exhibiting metal sulphur moieties in their active center.

Table of contents:

Part I: Primordial Metal–Sulfur-Mediated Reactions
Chapter 1: From Chemical Invariance to Genetic Variability
Chapter 2: Fe–S Clusters: Biogenesis and Redox, Catalytic, and Regulatory Properties

Part II: Model Complexes of the Active Site of Hydrogenases – Proton and Dihydrogen Activation
Chapter 3: [NiFe] Hydrogenases
Chapter 4: [FeFe] Hydrogenase Models: an Overview
Chapter 5: The Third Hydrogenase
Chapter 6: DFT Investigation of Models Related to the Active Site of Hydrogenases
Chapter 7: Mechanistic Aspects of Biological Hydrogen Evolution and Uptake

Part III: Nitrogen Fixation
Chapter 8: Structures and Functions of the Active Sites of Nitrogenases
Chapter 9: Model Complexes of the Active Site of Nitrogenases: Recent Advances
Chapter 10: A Unified Chemical Mechanism for Hydrogenation Reactions Catalyzed by Nitrogenase
Chapter 11: Binding Substrates to Synthetic Fe–S-Based Clusters and the Possible Relevance to Nitrogenases

Part IV: Miscellaneous: CO, RCN Activation, DMSO Reduction
Chapter 12: Sulfur-Oxygenation and Functional Models of Nitrile Hydratase
Chapter 13: Molybdenum and Tungsten Oxidoreductase Models

Part V: Applicative Perspectives
Chapter 14: Electrode Materials and Artificial Photosynthetic Systems

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Tags: Wolfgang Weigand, Philippe Schollhammer, Bioinspired, Complexes