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Catalytic Cascade Reactions 1st Edition by Peng Fei Xu 1118356640 9781118356647

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Catalytic Cascade Reactions 1st Edition Peng-Fei Xu Digital Instant Download

Author(s): Peng-Fei Xu, Wei Wang
ISBN(s): 9781118016022, 1118016025
Edition: 1
File Details: PDF, 25.51 MB
Year: 2013
Language: english
SKU: EB-4668800 Category: Tags: ,

Catalytic Cascade Reactions 1st Edition by Peng Fei Xu – Ebook PDF Instant Download/Delivery: 1118356640, 9781118356647
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ISBN 10: 1118356640
ISBN 13: 9781118356647
Author: Peng-Fei Xu

Demonstrates the advantages of catalytic cascade reactions for synthesizing natural products and pharmaceuticals Riding the wave of green chemistry, catalytic cascade reactions have become one of the most active research areas in organic synthesis. During a cascade reaction, just one reaction solvent, one workup procedure, and one purification step are needed, thus significantly increasing synthetic efficiency. Featuring contributions from an international team of pioneers in the field, Catalytic Cascade Reactions demonstrates the versatility and application of these reactions for synthesizing valuable compounds. The book examines both organocatalysis and transition-metal catalysis reactions, bringing readers up to date with the latest discoveries and activities in all major areas of catalytic cascade reaction research. Catalytic Cascade Reactions begins with three chapters dedicated to organocatalytic cascade reactions, exploring amines, Brønsted acids, and the application of organocatalytic cascade reactions in natural product synthesis and drug discovery. Next, the book covers: Gold-catalyzed cascade reactions Cascade reactions catalyzed by ruthenium, iron, iridium, rhodium, and copper Palladium-catalyzed cascade reactions of alkenes, alkynes, and allenes Application of transition-metal catalyzed cascade reactions in natural product synthesis and drug discovery Engineering mono- and multifunctional nanocatalysts for cascade reactions Multiple-catalyst-promoted cascade reactions All chapters are thoroughly referenced, providing quick access to important original research findings and reviews so that readers can explore individual topics in greater depth. Drawing together and analyzing published findings scattered across the literature, this book provides a single source that encapsulates our current understanding of catalytic cascade processes. Moreover, it sets the stage for the development of new catalytic cascade reactions and their applications.

Catalytic Cascade Reactions 1st Table of contents:

1 AMINE-CATALYZED CASCADE REACTIONS

1.1 INTRODUCTION

1.2 ENAMINE-ACTIVATED CASCADE REACTIONS

1.3 IMINIUM-INITIATED CASCADE REACTIONS

1.4 CYCLE-SPECIFIC CATALYSIS CASCADES

1.5 OTHER STRATEGIES

1.6 SUMMARY AND OUTLOOK

REFERENCES

2 BRØNSTED ACID–CATALYZED CASCADE REACTIONS

2.1 INTRODUCTION

2.2 PROTONIC ACID–CATALYZED CASCADE REACTIONS

2.3 CHIRAL THIOUREA (UREA)–CATALYZED CASCADE REACTIONS

2.4 BRØNSTED ACID AND TRANSITION METAL COOPERATIVELY CATALYZED CASCADE REACTIONS

2.5 CONCLUSIONS

REFERENCES

3 APPLICATION OF ORGANOCATALYTIC CASCADE REACTIONS IN NATURAL PRODUCT SYNTHESIS AND DRUG DISCOVERY

3.1 INTRODUCTION

3.2 AMINE-CATALYZED CASCADE REACTIONS IN NATURAL PRODUCT SYNTHESIS

3.3 BRØNSTED ACID–CATALYZED CASCADE REACTIONS IN NATURAL PRODUCT SYNTHESIS

3.4 BIFUNCTIONAL BASE/BRØNSTED ACID–CATALYZED CASCADE REACTIONS IN NATURAL PRODUCT SYNTHESIS

3.5 SUMMARY AND OUTLOOK

REFERENCES

4 GOLD-CATALYZED CASCADE REACTIONS

4.1 INTRODUCTION

4.2 CASCADE REACTIONS OF ALKYNES

4.3 CASCADE REACTIONS OF ALLENES

4.4 CASCADE REACTIONS OF ALKENES AND CYCLOPROPENES

4.5 CLOSING REMARKS

REFERENCES

5 CASCADE REACTIONS CATALYZED BY RUTHENIUM, IRON, IRIDIUM, RHODIUM, AND COPPER

5.1 INTRODUCTION

5.2 RUTHENIUM-CATALYZED TRANSFORMATIONS

5.3 IRON-CATALYZED TRANSFORMATIONS

5.4 IRIDIUM-CATALYZED TRANSFORMATIONS

5.5 RHODIUM-CATALYZED TRANSFORMATIONS

5.6 COPPER-CATALYZED TRANSFORMATIONS

5.7 MISCELLANEOUS CATALYTIC REACTIONS

5.8 SUMMARY

REFERENCES

6 PALLADIUM-CATALYZED CASCADE REACTIONS OF ALKENES, ALKYNES, AND ALLENES

6.1 INTRODUCTION

6.2 CASCADE REACTIONS INVOLVING ALKENES

6.3 CASCADE REACTIONS INVOLVING ALKYNES

6.4 CASCADE REACTIONS INVOLVING ALLENES

6.5 SUMMARY AND OUTLOOK

REFERENCES

7 USE OF TRANSITION METAL–CATALYZED CASCADE REACTIONS IN NATURAL PRODUCT SYNTHESIS AND DRUG DISCOVERY

7.1 INTRODUCTION

7.2 PALLADIUM-CATALYZED CASCADE REACTIONS IN TOTAL SYNTHESIS

7.3 RUTHENIUM-CATALYZED CASCADE REACTIONS IN TOTAL SYNTHESIS

7.4 GOLD- AND PLATINUM-CATALYZED CASCADE REACTIONS IN ORGANIC REACTIONS

7.5 COPPER- AND RHODIUM-CATALYZED CASCADE REACTIONS IN ORGANIC SYNTHESIS

7.6 SUMMARY

REFERENCES

8 ENGINEERING MONO- AND MULTIFUNCTIONAL NANOCATALYSTS FOR CASCADE REACTIONS

8.1 INTRODUCTION

8.2 HETEROGENEOUS MONOFUNCTIONAL NANOCATALYSTS

8.3 HETEROGENEOUS MULTIFUNCTIONAL NANOCATALYSTS

8.4 CONCLUSIONS AND PERSPECTIVES

REFERENCES

9 MULTIPLE-CATALYST-PROMOTED CASCADE REACTIONS

9.1 INTRODUCTION

9.2 MULTIPLE METAL CATALYST–PROMOTED CASCADE REACTIONS

9.3 MULTIPLE ORGANOCATALYST–PROMOTED CASCADE REACTIONS

9.4 METAL/ORGANIC BINARY CATALYTIC SYSTEM–PROMOTED CASCADE REACTIONS

9.5 SUMMARY AND OUTLOOK

REFERENCES

INDEX

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