Green Nanotechnology 1st Edition by Oleg Figovsky, Dmitry Beilin 9814774103 9789814774109

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ISBN 10: 9814774103 

ISBN 13: 9789814774109

Author: Oleg Figovsky, Dmitry Beilin

Green nanotechnology has two goals: producing nanomaterials and products without harming the environment or human health, and producing nanoproducts that provide solutions to environmental problems. It uses existing principles of green chemistry and green engineering to make nanomaterials and nanoproducts without toxic ingredients, at low temperatures using less energy and renewable inputs wherever possible, and using lifecycle thinking in all design and engineering stages. The production and process aspects of green nanotechnology involve both making nanomaterials in a more environmentally benign fashion and using nanomaterials to make current chemical processes more environmentally acceptable. This book contains information about advanced nanomaterials that can be produced without harming the environment or human health. This encompasses the production of nanomaterials without environmental toxicity, at room temperature and with the use of renewable energy sources. The book contains the descriptions and results of theoretical and experimental researches in the field of environment friendly nanotechnology carried out over the past decade by the scientific team of company Polymate Ltd.-International Nanotechnology Center (Israel) under leadership of Prof. O. Figovsky. Developments of the Company have been used in industry and agriculture and protected by more than 25 patents of USA, Germany and Russia.

Table of contents:

1. Nanostructured Composites Based on Interpenetrated Polymer Networks

1.1 Kinds, Classification, Properties, Synthesis, Application

1.1.1 Introduction

1.1.2 Kindsof IPNs

1.1.3 Classification of IPN [,]

1.1.3.1 IPN based on chemical bonding

1.1.3.2 IPN based on arrangement pattern

1.1.4 Properties of IPN [,]

1.1.5 Synthesis of Some IPN

1.1.5.1 Synthesis of IPN [, ,]

1.1.6 Dendripolymers Based on the Epoxy-Amine Reactions

1.1.7 Applications of IPN Technology

1.2 Nanostructured Liquid Ebonite Composition for Protective Coatings

1.2.1 Introduction

1.2.2 Structure and Properties of Oligobutadienes

1.2.3 Vulcanization

1.2.4 Strength and Hardness of Vulcanizate

1.2.5 Performance Characteristics of Vulcanizates

1.2.5.1 Thermomechanical properties

1.2.5.2 Sorption and diffusion properties

1.2.5.3 Chemical resistance

1.2.5.4 Adhesion stability of ebonite coatings

1.2.5.5 Electrochemical protection properties of ebonite coating

1.2.6 Technological Process of Manufacture and Properties of Ebonite Mixtures

1.2.6.1 One-pot composition

1.2.6.2 Double-pot composition

1.2.6.3 Examples of prepared LEM composition []

1.2.7 Applications of Ebonite Coatings

1.2.8 Conclusion

1.3 Nonisocyanate Polyurethanes Based on Cyclic Carbonates and Nanostructured Composites for Protective Coatings

1.3.1 Introduction

1.3.2 State of the Art in NIPU: Brief Description of the Latest Discoveries and Developments

1.3.3 Recent Achievements in the Field of NIPU

1.3.3.1 Polyhydroxyurethanes

1.3.3.2 Hybrid non-isocyanate polyurethanes

1.3.3.3 Application HNIPU for flooring and paints

1.3.3.4 UV curable HNIPU floorings and coatings

1.3.3.5 Hydroxyurethane modifiers

1.3.3.6 Hydroxyurethane compounds from renewable plant-based raw materials

1.3.3.7 Silane-containing and nanostructured hydroxyurethane compounds

1.3.3.8 Sprayable foam

1.3.4 Conclusion

2. Nanocomposites Based on a Hybrid Organosilicate Matrix

2.1 Introduction

2.2 Sol-Gel Technology

2.2.1 Alkoxide Method of Sol-Gel Synthesis

2.2.2 Nonhydrolytic Method of Sol-Gel Synthesis

2.2.3 Colloidal Method of Sol-Gel Synthesis

2.2.4 Soluble Silicates as Precursors Are in the Sol-Gel Technology of Nanocomposites

2.2.5 Preparation of Nanocomposites through Aerogels

2.2.6 Modification Products Sol-Gel Synthesis by Polyurethanes

2.3 Mixing Technologies of Nanocomposites

2.4 Different Types of Nanophases

2.4.1 Nanosized Filler

2.4.2 Nanosized Binder

2.4.3 Synthesis of Nanophase in the Matrix of the Composite Structure

2.5 Influence of Various Factors on Structure and Properties of Hybrid Materials

2.5.1 Packing of Spherical Nanoparticles of the Filler

2.5.2 Packing of Fibrous Nanoparticles of the Filler

2.5.3 Nanomaterials Based on Layered Particles

2.5.4 Special Organosilicate Additives and Modifiers

2.5.4.1 Tetrafurfuryloxysilane as a nanostructuring agent

2.5.4.2 Modification of an aqueous dispersion of chlorosulfonated polyethylene and other polymers compositions

2.5.4.3 Solid alumina-silicon flocculants-coagulants-matrix- isolated nanocomposites

2.6 Synthesis and Application of Hybrid Materials Based on Silica with Grafted Polymers

2.7 Conclusion

3. Polymer Nanocomposites with a High Resistance to an Aggressive Environment

3.1 Introduction

3.2 Modeling of Diffusion in Polymeric Materials

3.3 Modeling of Diffusion in a Random Porous System

3.4 Decrease of the Rate of Diffusion

3.5 Influence of Additives on the Operating Characteristics of Polymeric Materials

3.6 Development of Chemical Resistant Polymer Concretes

3.7 Application

3.8 Conclusions

4. Environmental Friendly Method of Production of Nanocomposites and Nanomembranes

4.1 Introduction

4.2 Brief Review of the Known Models of Superdeep Penetration

4.3 Investigations of Superdeep Penetration

4.4 Effects Appearing at Superdeep Penetration

4.4.1 Interaction Conditions Determining the Cratering Type

4.5 Expenditure of Energy in a Process of Superdeep Penetration

4.5.1 Clot of High-Speed Microparticles: Estimation of the Kinetic Energy

4.5.2 Formation of a Channel Structure during the Superdeep Penetration Process

4.5.3 Change of the Barrier Microstructure

4.5.4 Other Factors Causing Energy Expenditures

4.5.5 Energy Balance

4.6 SDP Method for “Green” Production Technology of Nanocomposites

4.6.1 Features of Dynamic Reorganization in Steel at Superdeep Penetration

4.6.2 Nanostructured Composites Based on a Metallic Matrix

4.6.3 Interaction of a Stream of Particles with Ceramics

4.6.4 Features of Interaction of a Stream of Discrete Particles with Plastic

4.6.5 Production of Polymer Nanocomposites

4.6.6 Development of New Porous Materials

4.6.7 Production of Polymer Tracking Membranes

4.7 Method for Treating Thin-Film Materials with a Flow of Solid Particles in the Electric Field

4.7.1 Charging and Acceleration of Solid Micro- and Nanoparticles by the Action of an Electrical Field

4.7.2 Production of Tracking Membranes by Accelerated Particles of Powders

4.8 Conclusions

5. Nanotechnology in the Production of Bioactive Paints, Coatings, and Food Storage Materials

5.1 Introduction

5.2 Production and Antimicrobial Characteristics of Nanoparticles of Silver

5.3 Experimental Investigation of New Bioactive Nanomodified Paints and Coatings

5.4 New Water-Dispersion Paint Composition with Biocide Properties

5.5 Nanosilver as a Potential Protective Material for Foodstuff

5.6 Conclusion

6. Green Nanostructured Biodegradable Materials

6.1 Introduction

6.2 Nanocellulose and Its Applications

6.2.1 Materials and Methods

6.2.2 Using of the Viscometry Method for NanoCell Investigations

6.2.3 Investigation of the NanoCell by the XRD Method

6.2.4 Method of Laser-Light Scattering

6.2.5 Using of the SEM Method for NanoCell Investigations

6.2.6 Potential Application, Preparation, and Investigation of Composite Materials Based on NanoCell

6.3 Processing of Biodegradable Packaging Materials

6.3.1 Biodegradable Packaging Material GreenCoatTM

6.3.2 Biodegradable Packaging Materials BHM

6.3.3 Basic Principles for Biodegradation of Polymers

6.3.4 Application of the Novel Biodegradable Packaging Materials

6.4 Nanocellulose as a Promising Biocarrier

6.4.1 Activity of the Nanocarrier

6.4.2 Applications of Cellulose Nanocarriers

6.5 Conclusion

7. Nanotechnology in Agriculture

7.1 Introduction

7.2 Biologically Active Multifunctional Nanochips and Method of Application for the Production of High-Quality Seed

7.2.1 Biologically Active Nanochips: Species and Compositions

7.2.2 Carriers, Stabilizers, and Solvents as the Components of BANs

7.2.3 Use of BANs for Treating Plant Seeds

7.2.4 Practical Preparation of Biologically Active Nanochips for Seed Germination

7.2.4.1 Composition of BANs for rice seed preparation for planting

7.2.4.2 Composition of BANs for wheat seed preparation for planting

7.4.2.3 Composition of BANs for cotton seed preparation for planting

7.2.4.4 Composition of BANs for sugar beet seed preparation for planting

7.4.2.5 Composition of BANs for soybean seed preparation for planting

7.2.4.6 Composition of BANs for corn seed preparation for planting

7.2.4.7 Composition of BANs for tomato seed preparation for planting

7.3 Detoxication of Pesticide and Other Toxic Substance in Soil by the Use of Nanomaterials

7.4 Application of Nanochips as Inducers of Disease Resistance during Presowing Seed Treatment

7.5 The Risks Connected with the Use of Polymeric Nanostructures in Technologies of Seed Treatment before Sowing

7.5.1 Toward Theory of Water Sorption by Seeds Using the Memory Functions Method

7.5.2 On Mechanisms of Water Transport into a Seed across the Polymer Cover

7.5.3 Role of the Polymer Cover in the Seed’s Water Sorption

7.5.4 The Seed as a Dissipative System

7.6 Conclusion

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Tags: Oleg Figovsky, Dmitry Beilin, Nanotechnology, Green