Iridium III in Optoelectronic and Photonics Applications 1st Edition by Eli Zysman Colman 1119007135 9781119007135

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ISBN 10: 1119007135 

ISBN 13: 9781119007135

Author: Eli Zysman-Colman

The fundamental photophysical properties of iridium(III) materials make this class of materials the pre-eminent transition metal complex for use in optoelectronic applications. Iridium(III) in Optoelectronic and Photonics Applications represents the definitive account of photoactive iridium complexes and their use across a wide variety of applications.  This two-volume set begins with an overview of the synthesis of these complexes and discusses their photophysical properties. The text highlights not only mononuclear complexes but also the properties of multinuclear and polymeric iridium-based materials and the assembly of iridium complexes into larger supramolecular architectures such as MOFs and soft materials. Chapters devoted to the use of these iridium-based materials in diverse optoelectronic applications follow, including: electroluminescent devices such as organic light emitting diodes (OLEDs) and light-emitting electrochemical cells (LEECs); electrochemiluminescence (ECL); bioimaging; sensing; light harvesting in the context of solar cell applications; in photoredox catalysis and as components for solar fuels. Although primarily targeting a chemistry audience, the wide applicability of these compounds transcends traditional disciplines, making this text also of use to physicists, materials scientists or biologists who have interests in these areas.

Table of contents:

1 Archetypal Iridium(III) Compounds for Optoelectronic and Photonic Applications: Photophysical Properties and Synthetic Methods

1.1 Introduction

1.2 Iridium Complex Ion Dopants in Silver Halide Photographic Materials

1.3 Overview of the Photophysical Properties of C^N and C^C: Cyclometalated Ir(III) Complexes

1.4 Importance of Ir─C Bonds in the Archetypal Ir(III) Complexes for Optoelectronic and Photonic Applications

1.5 Tuning Emission Color

1.6 Absorbance and Photoluminescence of C^N Cyclometalated Ir(III) Complexes

1.7 SOC Mechanism: Radiative Decay Rates and ZFS

1.8 Non‐Radiative Decay Rates

1.9 Synthetic Methods Targeting C^N Cyclometalated Ir(III) Compounds

1.10 Synthetic Methods for Cyclometalated Ir(III) Compounds Containing Carbenes

1.11 Conclusions

Acknowledgements

Abbreviations for Ligands in Ir(III) Complexes

References

2 Multinuclear Iridium Complexes

2.1 Introduction

2.2 Compounds Incorporating ‘Single Atom Bridges’: μ‐Chloro, μ‐Oxo and μ‐Aza

2.3 Polyatomic Acyclic Bridges: Acetylides, Cyanides and Hydrazides

2.4 Compounds with Heterocyclic Bridges

2.5 Multinuclear Complexes Featuring Conjugated Bridges between Iridium‐Bound Polypyridyl or Arylpyridyl Ligands

2.6 Concluding Remarks

Acknowledgements

References

3 Soft Materials and Soft Salts Based on Iridium Complexes

3.1 Introduction

3.2 Liquid Crystals

3.3 Gels

3.4 Micelles

3.5 Langmuir–Blodgett Films

3.6 Soft Salts

3.7 Conclusion

Acknowledgements

References

4 Porous Materials Based on Precious Metal Building Blocks for Solar Energy Applications

4.1 Introduction

4.2 The Luminescent Nature of MOFs and Their Use in Chemical Applications

4.3 Energy Transfer in Porous Materials

4.4 Porous Materials for Water Oxidation

4.5 Porous Materials for Proton Reduction

4.6 Porous Materials for CO2 Reduction

4.7 Conclusions and Outlook

References

5 Polymeric Architectures Containing Phosphorescent Iridium(III) Complexes

5.1 Introduction

5.2 Ir(III)‐Containing Polymers: Classification, Design Principles, and Syntheses

5.3 Hyperbranched and Dendritic Architectures

5.4 Concluding Remarks

References

6 Iridium(III) Complexes for OLED Application

6.1 Introduction

6.2 Iridium Complexes

6.3 Organic Light‐Emitting Diodes

6.4 Iridium(III) Complexes for PHOLED Application

6.5 Conclusions and Perspectives

References

7 A Comprehensive Review of Luminescent Iridium Complexes Used in Light‐Emitting Electrochemical Cells (LEECs)

7.1 Introduction

7.2 Device Fundamentals

7.3 Green Emitters

7.4 Blue Emitters

7.5 Yellow Emitters

7.6 Orange‐Red Emitters

7.7 Conclusions and Outlook

Acknowledgements

References

Volume 2

Title Page

List of Contributors

Foreword

Preface

8 Electrochemiluminescence of Iridium Complexes

8.1 Background and Overview of Electrochemiluminescence

8.2 Iridium ECL

List of Ligand Abbreviations Used in Text

References

9 Strategic Applications of Luminescent Iridium(III) Complexes as Biomolecular Probes, Cellular Imaging Reagents, and Photodynamic Therapeutics

9.1 Introduction

9.2 General Cellular Staining Reagents

9.3 Hypoxia Sensing Probes

9.4 Molecular and Ion Intracellular Probes

9.5 Organelle‐Targeting Bioimaging Reagents

9.6 Functionalized Polypeptides for Bioimaging

9.7 Polymers and Nanoparticles for Bioimaging

9.8 Photocytotoxic Reagents and Photodynamic Therapeutics

9.9 Conclusion

Acknowledgements

Abbreviations

References

10 Iridium Complexes in the Development of Optical Sensors

10.1 Generalities of Optical Sensors

10.2 Ir(III) Used as Optical Probes

10.3 Ir(III) Used in the Development of Sensing Phases

10.4 Conclusion and Future Challenges

Acronyms Used in the Names of the Complexes

References

11 Photoredox Catalysis of Iridium(III)‐Based Photosensitizers

11.1 Introduction

11.2 Iridium‐Based Photoredox Catalysis in Organic Synthesis

11.3 Conclusion

References

12 Solar Fuel Generation

12.1 Introduction

12.2 Fundamentals of [Ir(C^N)2(N^N)] Photosensitizers

12.3 Application of [Ir(C^N)2(N^N)] in Photocatalytic Water Reduction

12.4 Alternative Iridium Structures

12.5 Outlook

Acknowledgements

References

13 Iridium Complexes in Water Oxidation Catalysis

13.1 Introduction

13.2 Sacrificial Oxidants

13.3 Molecular Iridium Catalyst for Water Oxidation

13.4 Conclusions

Acknowledgements

Glossary of Terms and Abbreviations

References

14 Iridium Complexes as Photoactive Center for Light Harvesting and Solar Cell Applications

14.1 Introduction

14.2 Photoinduced Electron Transfer in Multicomponent Arrays

14.3 Iridium Complexes as Photoactive Center for Solar Cell Applications

14.4 Conclusions

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Tags: Eli Zysman Colman, Iridium, Optoelectronic, Photonics